THE COMPLETE PRACTICAL PAINTS PRODUCTION

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1.Emulsion  paints

2.Textured paints

3.Felxtured paints

4.Marble Trowel

5.Satin& Silk paints

6.Gloss paints

7.POP paints

8.Vinyl matt Emulsion

9.Fire Retardant paint

10.Anti Rust & primer coatings

11.Stucco paints

12.Pigment paste

13.Wall Filler

14.Screeding paints

15.Fluoresent paints

 

PAINT  TECHNOLOGY

 

PAINT : Is  defined as  a dispersion mixture of one  or  more substances in a vehicle.

VEHICLE : Is a liquid consisting of non-volatile film forming material, a volatile solvent called THINER and sometime an  oil.When paint is applied on a surface the thinner evaporated while the other components remain.

TYPES  OF PAINTS

1.      GLOSS OR OIL PAINT : These paints can only be thinned with organic or related Lacquer,Enamel,Industrial paints etc.They are based on natural or synthetic resins.

2.      EMULSION PAINTS (WATER BASED PAINTS): Paints that can be thinned with water are usually called Emulsion paints.They are matt,hard,durable, protective and absorbs heat due to  its porous nature.

3.      Generally,paints could be domestic,industrial,primer,surface or finish.

 

IMPORTANCE OF PAINTS

(a)   Beautification:Used to decorate

(b)   Protective: Protects surface.

(c)    Corrective: To cover or fill space

AREAS OF APPLICATION

(a)   Domestic :House,Furniture,Kitchen wares etc.

(b)   Industrial :Factories,Marine,Offices,Vehicles etc.

CONSTITUENTS OF PAINTS (RAW MATERIALS)

1.      RESIN : This is  the film forming part of paint.It also bind other components of paint to the surface.There are natural and synthetic resins.

Natural Resins

Synthetic Resin

1.Limseed Oil

Epoxy Resin

2.Castor Oil

Alkyd Resin

3.Tung Oil

Acrylic Resin

4.Rosine

Nitro Cellulose Resin

5.Fish Oil

Polyvinyl Acetate Resin

6.Soya Bean Oil

Polyurethane Resin

7.Rubber Seed

PVC Resin

Palm Kernel Oil etc.

Phenolic Resin etc.

 

2.      PIGMENTS/COLOURANTS :Pigment is a solid substance which give paint its desire colour.It also provides body to the paint.There are many types which are used solely or in combination with other  pigments.These could be organic or in-organic.

PIGMENT

COLOUR

TYPES

0PACITY

Titanium Dioxide

White

Inorganic

Very High

Zinc Oxide

  

  

Fairly  High

Lithophone

  

  

            

Aluminium Hydroxide

  

  

            

Ferric Oxide

Red

  

Very   High

Red Lead

  

  

            

Chrome Red

  

  

            

Rubine  Red

  

Organic

            

Prussian Blue

Blue

Inorganic

            

Phthalocyanine Blue

  

Organic

            

Chromium Oxide

Green

Inorganic

            

Halogen Green

  

Organic

            

Molybdate Oxide

Organic

Inorganic

            

Brown Umbre

Brown

   

            

Carbon Black

Black

   

            

Chrome Yellow

Yellow

Inorganic

            

Zinc Chromate

  

   

            

Litharge

 

   

HIGH

 

3.      EXTENDERS/FILLERS :These are cheap,low refractive materials added to paints to reduce cost, increase durability and give body to the paints.Examples of important extenders are talc, Barytes,Silica,Mica,Gypsum, Clay, Kaolin, Caicite, Calcium Carbonate, Magnesium Silicate etc.

4.      DRIERS : Driers are catalyst which carry oxygen (air) into the paint system. They accelerate the drying of the paint through oxidation,polymerization and condensation.Important driers are resinate, oleanatenaphthenates of Cobalt,Zinc, Calcium, Serelium,Lead, Manganese etc. Cobalt driers are the most efficient and are surface driers. Lead are bottom driers, Manganese,Zinc and some others are thoroughas surfactants and emulisfiers.Polyvinyl acetate based paints do not need driers as they are fast drying.

5.      EMULSIFIERS : There are soaps that help in dispersion/wetting of the soild components of the paint.They by their nature blend with both oil and non- oil (e.g water) materials zinc drier, sodium lecithin, soya lecithin,sodium lauryl sulphate,cetrimideetc.are good examples.

6.      THICKNER : Carboxylmethyl cellulose (CMC),Hyroxylmethyl cellulose such as Natrosol,Cellasize,Bermosol,Carbopol are common types. There are the organic ones. Inorganic ones include bentone,Easy Gel, Econogel etc.

7.      PLASTICIZERS : They provide elasticity,minimize cracking of the paint,make the paint to flow.Tricresylphosphate,Dioctylphthalate, Dibutyltartarate are  common example.They are very necessary in wood,Leather, metal and plastic paints.

8.      BIOCIDES : Chemicals that kill micro- organisms such as algae, fungi,mucour, etc are added into paints to prent it from decay.Emulsion paints usually contain these items Formalin,Cuppersulpate,Acticide, Pine Oil, Methyl paraben, Propyl paraben Acticide, Chloroxylenol,Cetrimide are used.There items are hardly  incoroporated into oil paints due to the fact that resins are rarely attacked by microbes.

9.      ANTIFOAMS: Pine Oil, Silicon Oil,Whitespirit,Kerosene, Gasoline are materials that can stop excessive foaming in paints systems.

10.  FLOATING AGENTS : CMC, Bentonite,Procol,Calceletc are some times added to paints to reduce the tendency for the solid water in  paints to settle at the bottom.

11.  ANTI SKINNING AGENTS : Oil paints have the tendency to gell  or skin.To avoid this wastage of paint polyhydraoxylphenols,oximes, Polyalkyl amines are incorporated in to the paints.

12.  OTHERS :Whitening agents such as tinapol,Aluminium Silicate are put,waxes such as Bee wax,carnubau wax, PJ, montan wax can also help the paint to set crack free.BUFFERS AND PRESERVATIVES such as sodium benzoate, sodium citrate, citric acid are sometimes employed to reduce undesired reactions in the paint, Starch, Protein Casein are used as Stabilizers.

13.  THINNERS & DILUENTS: These are very important solvents which reduce the viscosity of the paint; desolve the resins and solids suspend solids, help  in drying among others.They include: water,kerosene,Alcohol,Ketones,Acettates,Petroleum solvents Glycols etc.

 

Up to 80% of these raw material imputs in paint can be sourced locally. A 100% local raw material based paint is being tested.

 

QUALITIES OF A GOOD PAINT

1.      It must be fluid enough to enable easy application.

2.      It should posses high covering power

3.      It should form tough, uniform, adherent,impervious film.

4.      The film should not get cracked on drying.

5.      It  should protect/decorate the painted surface.

6.      It should form a lustre or clean film.

7.      The paint  should be stable and durable.

8.      It should not be poisonous to the user (for domestic paints mosly).

9.      It should have a good pot and shelf life.

10.  The paint should be the type that can be applied by one or more of the following methods:

(a)   Brushing (b) Rolling (c) Spraying (d) Dipping (e) Tumbling depending o n  the surface to be painted.

 

Any paint that does not meet the above standards is likely to fail by way of  CHALKING,FLAKING,CRACKING,CHANGE OF COLOUR OR UNAPPLICATION.

PAINTS RAW MATERIALS

1.      Resins (Synthetic) (2) Resin (Natural)

a.      Alkyd Resins                                                                     a.Linseed Oil

b.      Acrylic Resins                                                                   b.Soya Bean Oil

c.       Nitrocellulose Resin (NCR)                                            c. Coconut Oil

d.      Polyester Resins                                                              d. Castor Oil

e.      Polystyrene Resins                                                          e.Rosin

f.        Epoxy Resins, Phenolic etc.                                           f. Tall Oil

g.      P.V.A. (h) P.V.C.                                                               g.Fish Oil etc

h.Bitumen

 

       3.PIGMENTS

          Titanium Dioxide –White                                                      (4) Additivies (Natural)

          Zinc Oxide                                                                                 (A)Driers: C0,Zn,Pb,Mn,Ca,Al,

Aluminium Hydroxide                                                                 S e Salts.

        White Lead                                                               

        Lithophone                                                                                (B) Antiskinning Agents

 

      Carbon Black                                                                                    (1) Mekoximes

      Bitumen                                                                                             (2) Polyhydroxyphenols

Prucian Blue

     Halogens Various colours                                                                  (3) Polyhydroxyamines

     Red Oxide Dark Red                                                                            (4) Engenol

     Yellow Oxide Dark Yellow

     Lemon Chrome Bright Yellow                                                           (c) Plasticizers

     Middle Chrome                   

     Chromium Oxide Green                                                                     (1) Dioctylphosphate DOP

    Burnt Siena  Brown                                                                               (2) Tricresyphosphate TCP

   Van dyke                                                                                               (3) Tributylphthalate

   Litharge                                                                                                  (4) Dibutyltartarate  etc.

Rubine Bright Red

Molybdate Salt Orange                                                                           (D) Extenders or Fillers

 Venetian Red

 Lead Chromate Red to Orange                                                                (1) Gypsum

Yellow                                                                                                            (2) Talc

                                                                                                                         (3) Mica

5.Solvents & Diluents(Thinners)                                                                 (4) Limestone

A.Aliphatics                                                                                                   (5) Barytes

    White Spirit                                                                                                (6) Chinaclay

    Kerosene                                                                                                     (7) kaolin

    Petrol                                                                                                           (8) Diatomite

 Gasoline                                                                                                             (9)Silica  etc .

Hexane etc.

                                                                                                                            (E) Antifoams

B. Aromatics                                                                                                      (1) Silicon Oil

     Toluene                                                                                                         (2) Pine Oil

    Xylene                                                                                                             (3) Glycols

    Naphthalene

    Turpentine                                                                                                      (F) Dispersants

Aromasol                                                                                                            (1) Soya Licithin

                                                                                                                                 (2) Soaps (Natural)

C. Alcohols                                                                                                            (3) Detergents (Natural)

                                                                             (4)PA1000

    Ethanol                                                                                                               (5) Clycol Ester etc.

Isoprophylalcohol, IPa

Isobutylalcohol  SBA                                                                                        (G) Thickners

    Butanol                                                                                                               (1) Hydroxycellulose

    Propanol                                                                                                             (2) Hexanol

    Methanol                                                                                                            (3) Bentonited

                                                                                                                                  (4) Polygeletc .

   5.D. Esters                                                                                                         (4.H.) Biocides

       Ethyl Acetate                                                                                                  (1)   Pine Oil

       Butyl Acetate                                                                                                    (2)    Acticide

       Propyl Acetate                                                                                                  (3)    Formalin

       Isobutyl Acetate                                                                                                (4)    Copper  Sulphate

   E. Ketsones                                                                                                     (I) Preservatives

       Acetone                                                                                                       (1)  Sodium Benzoate

Methylethyketone MEK                                                                             (2) Methyl Paraben

Methylisobutylketone, MIBK                                                                    (3) Propyl Paraben

                                                                                                                               (4) Ammonia etc.

F. Glycols                                                                                                              (J)  Waxes

Oxitol                                                                                                                    (1) Beewax,Linolin,

Carnubawax

polyethene wax.

Ethylglycol

Butylglycol

Butyloxitol

Ethlglycol acetate.

6. Chlorinated Hydrocarbons

Carbontetrachloride (Chloroform)

Trichloroethane etc.

 

 

 

PAINT PRODUCTION MACHINE

Paint being of thin vehicle system compared to paste may be prepared in

(a)   Tripple roll mill with contact rollers.

(b)   Ball mills (Bead,pebble mill)

(c)    Shot mill

(d)   Sand mill

(e)   Speed mixers etc.

However, where solvent or volatile materials are negligible or absent shot mills  and other  open-style intensive mixing systems may be used together with speed mixers.

The choice of equipment for paint production  or manufacture ultimately depends on;

(a)   The volume to be produced

(b)   The pigment hardness

(c)    Presence or lack of volatile solvents etc

(d)   The body or viscosity of the finished product.

(e)   The method of application of the paint could also be considered.

The manchine are locally available now: information on machines are available on request.

 

                    SOME INK/PAINT LABORATORY TEST EQUIPMENT/TOOLS

S/NO

EQUIPMENT/TOOL

                  APPLICATION

REMARK

1.

Grind Gauge

For checking degree of dispersion(grinding)

Simple to handle

2.

Draw-down kit

For checking colour match

          

3.

Palatte& knives

For mixing & handling paints

          

4.

Weighing scale

For weighing materials

          

5.

A colour chart

For Refering to standard colours

          

6.

A slab

For working on colours

          

7.

A stop watch

For timing

          

8.

A viscosity cup

For testing viscosity

          

9.

Glass wares

For General laboratory work

          

10.

A density Bottle or equipment

For checking density

Needs expertise

11.

A Band Tester

For Hardness Elasticity

          

 

 

PAINT  PRODUCTION

The “Chemist” must consider all available option in  terms of the factors below when formulating paints.Viz:

(a)   Cost of production

(b)   Ease of production

(c)    End users requirement

(d)   Raw materials available

When a specific formula has been developed the stages of production is then followed to enable him arrive at a good product.

Before the full scale batch is made it is very necessary that the following pre-production basic are done.

1.      COLOUR MATCHING: At the “test tube” level the appropriate colour required is developed and checked before the batch is made by scaling up the values obtained during colour matching.

2.      PIGMENT/SOLID COMPONENTS HARDNESS: If the hardness of the pigments/solids to be used are know, a lot of time,energy and labour will be saved by using appropriate methods.

3.      WEIGHING:  Accuracy in weights taken saves money and gives good products. The weight master must be well trained and should be a careful hand.It is necessary to check the weighing scale each time  a new weight is to be taken.Errors in weight in paint making bring about off- shade and its attendant wastage and higher costs.

  • Availability: In Stock

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