- LAUNDRY AND BAR SOAP
- TOILET SOAP
- MEDICATE SOAP
- ANTISEPTIC SOAP
- DETERGENT
- LIQUID DETERGENT
- TILES CLEANER
SOAPS
Soaps and detergents belong to the same group of chemical products called surface active agents or surfactants.These groups of products are among other properties,well -known for their detergency which is due to a reduction in water surface tension which remove the dirt by wetting,emulsification,lathering and removal.
Soaps generally are produced through a reaction know as saponification.This reaction occurs when fats and oil are hydrolised in alkaline (basic) solution.In other words it is alkaline hydrolysis of fats and oil.The result of this is the formation of glycerol and salts of the fatty acids.The sodium or potassium salts formed is the soap.
The cleansing activity of soap could be explained in terms of its molecule structure.Actually water can wash off some thingwith out application of soap.For instance if a sticky sugar syrup is poured on somebody's hand , water is used to wash it off ,the sugar dissolves in the water and is rinsed off.If there is a case where oil is poured,water used to wash it will just run off the surface of the oil.Other dirt though not oil could form greasy film together over the skin or clothes (as case may be) there by making it difficult for the water to wash off . When soap solution is applied to a grease -coated piece of fabric ,the soap molecules first approach the grease spot at the inter-phase of the grease and water.The hydrophobic(water hating)tail of the soap particles dissolves in the grease while the hydrophilic (water loving) head dissolves in the water .The water molecules attract the polar ionic heads of the soap molecules .This action helps to lift the grease spot upwards, enabling more soap particles to dissolve in the grease .
Eventually with mechanical scrubbing, the grease patch is emulsified.On rinsing the fabric ,the grease is removed.
There are different ways (processes) in the production of soap.They are:
1.Cold process
2.Semi- Boiled process
3.Full- Boiled process
Cold process: Here heating is not involved.It is the most elementary batch process.In a saponification vessel (mixer)it involved the gradual addition of right quantity of soda iye (aqueous sodium hydroxide) to fats and oil.The mixture is kept under vigorous agitation (mixing) for approximately two hairs,and the dyes, perfume and additives are generally added at this stage.This process does not include the removal of impurities or separation of the glycerine which is produced.
Crude soap is drawn off as soon as the bulk of the mixture thickens, and is poured into the cooling frames where the saponification process continues for one or more days.Crude soap is then removed from the frame,cut in sizes and put into mould.
The process is simple,inexpensive and not highly mechanised.It requires only modest investment in equipment.Low-grade soaps are produced through this method.
Semi- boiled process- this differs from the cold process in the fact that the saponnification mixture(fats and oil and caustic soda solution) is heated to 70-900C.Dye, perfumes and additives are added at the end of the processs to prevent them from evaporating.Generallyspeaking,saponification is more complete and the hardening time of crude soap in cooling frame is slightly reduced.
The process allows the quantity of soda undergoing saponification to be adjusted before the crude soap is drawn off .It allows the manufacturing waste to be recycled,better incorporation of the additives and wider choice of raw materials .
Full-Boild process-This process differs from semi-boiled process in its various glycerineextraction,wash and adjusment operations which occurs after saponification.The temperature at which the mixture is kept under vigorous agitation is generally higher(1000C),allowing a wider range of fatty raw materials to be used.
After saponification,the mass is subjected to several washes using brine.The more intensely the glycerine is washing water drawn off several times, glycerine concentrations in the region of 15-20% can be obtained.
The cooling and drying of soap
Once saponification has been completed,the soap obatined whether crude or neat,has to be turned into marketable soap.This is the cooling and drying stage,which gives the end product the required consistency and hardness.Household soap generally contains 25% water (75% Fatty acids) where as toilet soap undergoes forced drying until it contains only 14% or even 12% water (86 to 88%) fatty acids).
Crude soap produces a lower-quality,inexpensivesoap.That is why it does not usually undergo any drying other than air drying,which is carried out over serveral day in cooling frames
Cold process | Semi-boild process | Full-boild process | |
Types of soap | Low-grade household soap | Standard household soap | Standard to grade toilet and laundry soap |
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